Surface and Interfacial Forces

1 INTRODUCTION

2 VAN DER WAALS FORCES
2.1 Van der Waals Forces Between Molecules
2.2 The Van der Waals Force Between Macroscopic Solids
2.3 The Derjaguin Approximation
2.4 Retarded Van der Waals Forces
2.5 Measurement of Van der Waals Forces
2.6 The Casimir Force
2.7 Summary
2.8 Exercises

3 EXPERIMENTAL METHODS
3.1 Surface Forces Apparatus
3.2 Atomic Force Microscope
3.3 Optical Tweezers
3.4 Total Internal Re¿ection Microscopy
3.5 Magnetic Tweezers
3.6 Summary
3.7 Exercises

4 ELECTROSTATIC DOUBLE-LAYER FORCES
4.1 The Electric Double Layer
4.2 Poisson?Boltzmann Theory of the Diffuse Double Layer
4.3 Beyond Poisson?Boltzmann Theory
4.4 The Gibbs Energy of the Electric Double Layer
4.5 The Electrostatic Double-Layer Force
4.6 The DLVO Theory
4.7 Electrostatic Forces in Nonpolar Media
4.8 Summary
4.9 Exercises

5 CAPILLARY FORCES
5.1 Equation of Young and Laplace
5.2 Kelvin Equation and Capillary Condensation
5.3 The Young?s Equation
5.4 Capillary Forces Calculated with the Circular Approximation
5.5 In¿uence of Roughness
5.6 Kinetics of Capillary Bridge Formation and Rupture
5.7 Capillary Forces in Immiscible liquid Mixtures and Other Systems
5.8 Lateral Forces Between Particles at a Fluid Interface
5.9 Summary
5.10 Exercises

6 HYDRODYNAMIC FORCES
6.1 Fundamentals of Hydrodynamics
6.2 Hydrodynamic Force between a Solid Sphere and a Plate
6.3 Hydrodynamic Boundary Condition
6.4 Gibbs Adsorption Isotherm
6.5 Hydrodynamic Forces Between Fluid Boundaries
6.6 Summary
6.7 Exercises

7 INTERFACIAL FORCES BETWEEN FLUID INTERFACES AND ACROSS THIN FILMS
7.1 Overview
7.2 The Disjoining Pressure
7.3 Drainage
7.4 Thin Film Balance
7.5 Interfacial Forces Across Foam and Emulsion Films
7.6 Thin Wetting Films
7.7 Summary
7.8 Exercises

8 CONTACT MECHANICS AND ADHESION
8.1 Surface Energy of Solids
8.2 Contact Mechanics
8.3 In¿uence of Surface Roughness
8.4 Adhesion Force Measurements
8.5 Summary
8.6 Exercises

9 FRICTION
9.1 Macroscopic Friction
9.2 Lubrication
9.3 Microscopic Friction: Nanotribology
9.4 Summary
9.5 Exercises

10 SOLVATION FORCES AND NON-DLVO FORCES IN WATER
10.1 Solvation Forces
10.2 Non-DLVO Forces in an Aqueous Medium
10.3 The Interaction Between Lipid Bilayers
10.4 Force Between Surfaces with Adsorbed Molecules
10.5 Summary
10.6 Exercises

11 SURFACE FORCES IN POLYMER SOLUTIONS AND MELTS
11.1 Properties of Polymers
11.2 Polymer Solutions
11.3 Steric Repulsion
11.4 Polymer-Induced Forces in Solutions
11.5 Bridging Attraction
11.6 Depletion and Structural Forces
11.7 Interfacial Forces in Polymer Melts
11.8 Summary
11.9 Exercises

12 SOLUTIONS TO EXERCISES

Hans-Jürgen Butt studied physics in Hamburg and Göttingen, Germany. Then he went to the Max-Planck-Institute of Biophysics in Frankfurt. After receiving his Ph.D. in 1989 he went as a post-doc to Santa Barbara, California, using the newly developed atomic force microscope. From 1990-95 he spent as a researcher back in Germany at the Max-Planck-Institute for Biophysics. In 1996 he became associate professor for physical chemistry at the University Mainz, three years later full professor at the University of Siegen. Two years later he joined the Max-Planck-Institute of Polymer Research in Mainz and became director for Experimental Physics.

Michael Kappl received his PhD thesis from the Max-Planck-Institute of Biophysics in Frankfurt and worked at the University of Mainz and Siegen. Since 2002 he is a project leader at the Max-Planck-Institute for Polymer Research in Mainz. He concentrates his research activities on Surface Forces and the Interactions of Particle Bubbles as well as Monolayer Particles.

H.-J. Butt, MPI for Polymer Research, Mainz, Germany; M. Kappl, MPI for Polymer Research, Mainz, Germany