John Wiley & Sons Phosphorus: The Carbon Copy Cover Ninety-five percent of modern organic chemistry concerns carbon. In the past, silicon has been used .. Product #: 978-0-471-97360-7 Regular price: $523.36 $523.36 Auf Lager

Phosphorus: The Carbon Copy

From Organophosphorus to Phospha-Organic Chemistry

Dillon, Keith B. / Mathey, François / Nixon, John F.

Cover

1. Auflage Januar 1998
X, 366 Seiten, Hardcover
Wiley & Sons Ltd

ISBN: 978-0-471-97360-7
John Wiley & Sons

Kurzbeschreibung

Ninety-five percent of modern organic chemistry concerns carbon. In the past, silicon has been used as a carbon substitute but this book, by two of the leading researchers in the field of modern coordination chemistry, states that phosphorus is more similar to carbon and can be readily used as a substitute. This concise work is divided into two sections: the first focusing on multiple bonded phosphorus compounds, as well as phosphorus-metal complexes; the second on phosphoranides and their metal complexes, five and six-coordinated cationic, neutral and anionic compounds.

Im Mittelpunkt dieser aktuellen Monographie steht der Austausch von Kohlenstoff organischer Verbindungen durch Phosphor. Die Autoren postulieren dabei, daß infolge der Schrägbeziehung im Periodensystem Kohlenstoff wesentlich mehr Analogien zu Phosphor aufweist als zu Silicium. Diskutiert werden insbesondere Phosphorverbindungen mit Mehrfachbindungen und ihre Metallkomplexe (Teil 1) sowie eine breite Palette von Organophosphorverbindungen (Teil 2). (12/97)

Introduction; Phosphinidenes; Terminal Phosphinidene Complexes: Electrophilic 2-Electron Complexes; Nucleophilic 2-Electron Complexes; 4-Electron Complexes; Phosphaalkynes; Phosphaalkenes; Phosphapolyenes: Conjugated Phosphadienes and their Cycloaddition Chemistry; Phosphacumulenes (RP=(C)n=CR'2); Phosphaketenes (RP=C=O); Diphosphenes; Phosphorus - Carbon Heterocyclic Chemistry: Phosphiranes and Phosphirenes; Phospholes; Phospholide and Polyphospholide Anions; Phosphinines; p-Coordination: Pholphaallyl Anions, h3-Phosphaallyl and h3-Phosphirenyl Complexes; h4-Phosphadiene and h4-Phosphacyclobutadience Complexes; h5-Phospholyl Complexes; h5-Polyphospholyl Complexes; h6-Phosphinine Complexes; Conclusions.