Mossbauer Spectroscopy

Preface xix

Contributors xxi

Chapter 1 In-Situ Mössbauer Spectroscopy with Synchrotron Radiation on Thin Films 3
S Stankov, T Zl'zak, M Zajc, M Zl'zak, M Sladecek, R Röhlsberger, B. Sepiol, G Vogl, N Spiridis, J Aa|ewski, K ParliDski, and J Korecki

1 1 Introduction 3

References 39

Chapter 2 Mössbauer Spectroscopy in Studying Electronic Spin and Valence States of Ironin the Earth's Lower Mantle 43
Jung-Fu Lin, Zhu Mao, and Ercan E Alp

Acknowledgments 55

References 55

Chapter 3 In-beam Mössbauer Spectroscopy Using a Radioisotope Beam and a Neutron Capture Reaction 58
Yoshio Kobayashi

3 .4 Summary 66

References 67

Part II Radionuclides 71

Chapter 4 Lanthanides(151Eu and 155Gd)-Mössbauer Spectroscopic Study of Defect-FluoriteOxides Coupled with New Defect-Crystal-Chemistry Model 73
Nakamura, N Igawa, Y Okamoto, Y Hinatsu, J, Wang, M Takahashi and M. Takeda

Conclusion 92

References 93

Chapter 5 Mössbauer and Magnetic Study of Neptunyl(+1) Complexes 95
T Nakamoto, A Nakamura and M Takeda

Conclusion 113

Acknowledgment 113

References 113

Chapter 6 Mössbauer Spectroscopy of 161Dy in Dysprosium Dicarboxylates 116
M Takahashi, C I Wynter, B R Hillery, Virender K Sharma, D Quarless, Leopold May, T Misu, S G Sobel, M Takeda, and E Brown

Acknowledgment 122

References 122

Chapter 7 Study of Exotic Uranium Compounds using 238U Mössbauer Spectroscopy 123
Satoshi Tsutsui 1,2 and Masami Nakada 1

Summary 137

Acknowledgment 138

References 138

Part III Spin Dynamics 141

Chapter 8 Reversible Spin-state Switching Involving a Structural Change 143
Satoru Nakashima

References 151

Chapter 9 Spin- Crossover and Related Phenomena Coupled with Spin, Photon and Charge
152
N Kokima and A Sugahara

9 3 Charge Transfer Phase Transition 161

9 4 Spin Equilibrium and Succeeding Phenomena 168

References 175

Chapter 10 Spin Crossover in Iron(III) Porphyrins Involving the Intermediate-Spin State 177
Mikio Nakamura and Masashi Takahashi

Acknowledgments 198

References 199

Chapter 11 Tin(II) Lone Pair Stereoactivity: Influence on Structures and Properties, and Mössbauer Spectroscopic Properties 202
Georges Dénès, M Cecilia Madamba, Hocine Merazigand Abdualhafed Muntasar

216

Acknowledgments 243

References 243

Part IV Biological Applications 247

Chapter 12 Synchrotron Radiation Based Nuclear Resonant Scattering: Applications to Bioinorganic Chemistry 249
Yisong Guo, Yoshitaka Yoda, Xiaowei Zhang, Yuming Xiao, Stephen P Cram

Acknowledgment 269

References 269

Chapter 13 Mössbauer Spectroscopy in Biological and Biomedical Research 272
Alexander A Kamnev,*, Krisztina Kovács, Irina V Alenkina, and Michael I. Oshtrakh

Acknowledgments 287

References 287

Chapter 14 Controlled Spontaneous Decay of Mossbauer Nuclei (Theory and Experiments) 292
Vladimir I Vysotskii and Alla A Kornilova

References 314

Chapter 15 Natural's Strategy to Oxidize Tryptophan: EPR and Mossbauer Characterization of High-Valent Fe Intermediates 315
Kednerlin Dornevil and Aimin Liu

References 322

Chapter 16 Iron in Neurodegeneration 324
Jolanta GaBzka-Friedman, Erika R Bauminger, and Andrzej Friedman

References 331

Chapter 17 Emission (57Co) Mössbauer Spectroscopy: Biology-related Applications, Potentials and Prospects 333
Alexander A Kamnev

Acknowledgments 345

References 346

Part V Iron Oxides 349

Chapter 18 Mossbauer Spectroscopy in Study of Nanocrystalline Iron Oxides from Thermal Processes 351
JiYí Tu ek, Libor Machala, JiYí Frydrych, JiYí Pechousek, and Radek ZboYil

Acknowledgment 389

References 389

Chapter 19 Transmission and Emission 57Fe Mössbauer Studies on Perovskites and Related Oxide Systems 393
Zoltán Homonnay and Zoltán Németh

References 413

Chapter 20 Enhancing the Possibilities of 57Fe Mössbauer Spectrometry to Study the Inherent Properties of Rust Layers 415
Karen E García, César A Barrero, Alvaro L Morales, and Jean-Marc Greneche

Acknowledgments 426

References 426

Chapter 21 Application of Mössbauer Spectroscopy in Nanomagnetics 429
Lakshmi Nambakkat

Conclusion 452

Acknowledgment 453

References 453

Chapter 22 Mössbauer Spectroscopy and Surface Analysis 455
José F Marco, J Ramón Gancedo, Matteo Monti and Juan de la Figuera

Acknowledgments 468

References 468

Chapter 23 57Fe Mössbauer Spectroscopy in the Investigation of the Precipitation of Iron Oxides
470
Svetozar Music, Mira Ristic, and Stjepko Krehula

Acknowledgment 496

References 497

Chapter 24 Ferrates (IV, V, and VI): Mössbauer Spectroscopy Characterization 505
Virender K Sharma, Yurii Perfiliev, Radek Zboril, Libor Machala, and Clive Wynter

Acknowledgments 517

References 517

Chapter 25 Characterization of Dilute Iron-Doped Yttrium Aluminum Garnets by Mössbauer Spectrometry 521
Kiyoshi Nomura and Zoltán Németh

Conclusion 531

Acknowledgment 532

References 532

Part VI Industrial Applications 533

Chapter 26 Some Mössbauer Studies of Fe-As Based High Temperature Superconductors 535
Amar Nath and Airat Khasanov

Acknowledgment 541

References 541

Chapter 27 Mossbauer Study of New Electrically Conductive Glass 542
Tetsuaki Nishida and Shiro Kubuki

Acknowledgments 551

References 551

Chapter 28 Applications of Mössbauer Spectroscopy in the Study of Lithium Battery Materials 552
Ricardo Alcántara, Pedro Lavela, Carlos Pérez Vicente, José L Tirado

Conclusions 561

Acknowledgment 561

References 562

Chapter 29 Mössbauer Spectroscopic Investigations of Novel Bimetal Catalysts for Preferential CO Oxidation in H2 564
Wansheng Zhang, Junhu Wang, Kuo Liu, Jie Jin, and Tao Zhang

Conclusion 574

Acknowledgments 574

References 575

Chapter 30 The use of Mossbauer Spectroscopy in Coal Research-Is it Relevant or Not? 576
F B Waanders

Conclusions 590

References 591

Part VII Environmental Applications 593

Chapter 31 Water Purification and Characterization of Recycled Iron-Silicate Glass 595
Shiro Kubuki and Tetsuaki Nishida

Reference 606

Chapter 32 Mössbauer Spectroscopy in the Study of Laterite Mineral Processing 608
Eamonn Devlin, Michail Samouhos, Charalabos Zografidis

Reference 619

Index 621