The Chemistry of Heterocyclic Compounds
Volume 62: The Chemistry of 1,2,3-Thiadiazoles
The Chemistry of Heterocyclic Compounds (Band Nr. 62)
1. Auflage Mai 2004
272 Seiten, Hardcover
Wiley & Sons Ltd
ISBN:
978-0-471-32662-5
John Wiley & Sons
Kurzbeschreibung
1,2,3-Thiadiazoles are a group of heterocycles whose derivatives are important in industry, medicine, and agriculture. This volume provides a complete treatment of this group of heterocycles with an emphasis on syntheses, structural data, properties, reactions, and applications.
1,2,3-Thiadiazoles are a group of heterocycles whose derivatives are important in industry, medicine, and agriculture. This volume provides a complete treatment of this group of heterocycles with an emphasis on syntheses, structural data, properties, reactions, and applications.
1 Synthesis of 1,2,3-thiadiazoles.
1.1 Cyclization of Hydrazones with Thionyl Chloride (Hurd-Mori Synthesis).
1.2 Cycloaddition of Diazoalkanes onto a C=S bond (Pechmann Synthesis).
1.3 Heterocyclization of ±-diazo Thiocarbonyl Compounds (Wolff Synthesis).
1.4 Transformations of other Sulfur-containing Heterocyclic Compounds.
1.5 Elaboration of Preformed 1,2,3-Thiadiazoles.
1.6 Tables.
1.7 Selected Procedures.
References.
2 Structure of 1,2,3-Thiadiazoles.
2.1 Theoretical Methods.
2.2 Experimental Structural Methods.
References.
3 Chemical Properties of 1,2,3-Thiadiazoles.
3.1 Reactions due to the Reactivity of Ring Atoms.
3.2 Reactions of Substituents.
3.3 Rearrangements.
3.4 Ring Cleavage of 1,2,3-Thiadiazoles.
References.
4 Fused 1,2,3-Thiadiazoles.
4.1 1,2,3-Thiadiazoles Fused with Five-Membered Rings.
4.2 1,2,3-Thiadiazoles Fused with Six-Membered Rings.
4.3 1,2,3-Thiadiazoles Fused with Seven-Membered Rings.
4.4 Bicyclic 1,2,3-Thiadiazoles of Azathiapentalenic Structure.
References.
5 Synthesis and Properties of 1,2,3-Selenadiazoles.
5.1 Synthesis of 1,2,3-Selenadiazoles.
5.2 Structural Data of 1,2,3-Selenadiazoles.
5.3 Reactivity of 1,2,3-Selenadiazoles.
5.4 Fused 1,2,3-Selenadiazoles.
5.5 Applications of 1,2,3-Selenadiazoles.
References.
6 1,2,3-Thiadiazoles in Medicine and Agriculture.
6.1 Medicine.
6.2 Agriculture.
References.
Index.
1.1 Cyclization of Hydrazones with Thionyl Chloride (Hurd-Mori Synthesis).
1.2 Cycloaddition of Diazoalkanes onto a C=S bond (Pechmann Synthesis).
1.3 Heterocyclization of ±-diazo Thiocarbonyl Compounds (Wolff Synthesis).
1.4 Transformations of other Sulfur-containing Heterocyclic Compounds.
1.5 Elaboration of Preformed 1,2,3-Thiadiazoles.
1.6 Tables.
1.7 Selected Procedures.
References.
2 Structure of 1,2,3-Thiadiazoles.
2.1 Theoretical Methods.
2.2 Experimental Structural Methods.
References.
3 Chemical Properties of 1,2,3-Thiadiazoles.
3.1 Reactions due to the Reactivity of Ring Atoms.
3.2 Reactions of Substituents.
3.3 Rearrangements.
3.4 Ring Cleavage of 1,2,3-Thiadiazoles.
References.
4 Fused 1,2,3-Thiadiazoles.
4.1 1,2,3-Thiadiazoles Fused with Five-Membered Rings.
4.2 1,2,3-Thiadiazoles Fused with Six-Membered Rings.
4.3 1,2,3-Thiadiazoles Fused with Seven-Membered Rings.
4.4 Bicyclic 1,2,3-Thiadiazoles of Azathiapentalenic Structure.
References.
5 Synthesis and Properties of 1,2,3-Selenadiazoles.
5.1 Synthesis of 1,2,3-Selenadiazoles.
5.2 Structural Data of 1,2,3-Selenadiazoles.
5.3 Reactivity of 1,2,3-Selenadiazoles.
5.4 Fused 1,2,3-Selenadiazoles.
5.5 Applications of 1,2,3-Selenadiazoles.
References.
6 1,2,3-Thiadiazoles in Medicine and Agriculture.
6.1 Medicine.
6.2 Agriculture.
References.
Index.
