Rhodium Catalysis in Organic Synthesis
Methods and Reactions
1. Edition March 2019
688 Pages, Hardcover
Handbook/Reference Book
Short Description
The use of Rhodium catalysis has increased dramatically during the last decade, so that a range of highly useful reaction types like coupling reactions, cyclizations and many more are performed efficiently. Ken Tanaka presents this field comprehensively in this reference.
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An essential reference to the highly effective reactions applied to modern organic synthesis
Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations. Rhodium Catalysis in Organic Synthesis explores the most recent progress and new developments in the field of catalytic cyclization reactions using rhodium(I) complexes and catalytic carbon-hydrogen bond activation reactions using rhodium(II) and rhodium(III) complexes.
Edited by a noted expert in the field with contributions from a panel of leading international scientists, Rhodium Catalysis in Organic Synthesis presents the essential information in one comprehensive volume. Designed to be an accessible resource, the book is arranged by different reaction types. All the chapters provide insight into each transformation and include information on the history, selectivity, scope, mechanism, and application. In addition, the chapters offer a summary and outlook of each transformation. This important resource:
-Offers a comprehensive review of how rhodium complexes catalyze a variety of highly useful reactions for organic synthesis (e.g. coupling reactions, CH-bond functionalization, hydroformylation, cyclization reactions and others)
-Includes information on the most recent developments that contain a range of new, efficient, elegant, reliable and useful reactions
-Presents a volume edited by one of the international leading scientists working in the field today
-Contains the information that can be applied by researchers in academia and also professionals in pharmaceutical, agrochemical and fine chemical companies
Written for academics and synthetic chemists working with organometallics, Rhodium Catalysis in Organic Synthesis contains the most recent information available on the developments and applications in the field of catalytic cyclization reactions using rhodium complexes.
Rhodium(I)-Catalyzed Asymmetric Hydrogenation
Rhodium(I)-Catalyzed Hydroboration and Diborylation
Rhodium(I)-Catalyzed Hydroformylation and Hydroamination
Rhodium(I)-Catalyzed Hydroacylation
Rhodium(I)-Catalyzed (Asymmetric) Addition of Organometallic Reagents to Unsaturated Compounds
Rhodium(I)-Catalyzed Allylation with Alkynes and Allenes
Rhodium(I)-Catalyzed Reductive Carbon-Carbon Bond Formation
Rhodium(I)-Catalyzed [2+2+1] and [4+1] Cycloadditions
Rhodium(I)-Catalyzed [2+2+2] and [4+2] Cycloadditions
Rhodium(I)-Catalyzed Annulation Involving Vinylcyclopropanes
Rhodium(I)-Catalyzed Reactions via Carbon-Hydrogen Bond Cleavage
Rhodium(I)-Catalyzed Reactions via Carbon?Carbon Bond Cleavage
RHODIUM(II) CATALYSIS
Rhodium(II) Tetracarboxylate-Catalyzed Enantioselective C?H Functionalization Reactions
Rhodium(II)-Catalyzed Nitrogen-Atom Transfer for Oxidation of Aliphatic C?H Bonds
Rhodium(II)-Catalyzed Cyclopropanation
Reactions of alpha-Imino Rhodium(II) Carbene Complexes Generated from N-Sulfonyl-1,2,3-Triazoles
Rhodium(II)-Catalyzed 1,3- and 1,5-Dipolar Cycloaddition
RHODIUM(III) CATALYSIS
Rhodium(III)-Catalyzed Annulative Carbon-Hydrogen Bond Functionalization
Rhodium(III)-Catalyzed Non-Annulative Carbon-Hydrogen Bond Functionalization
Sterically and Electronically Tuned Cp Ligands for Rhodium(III)-Catalyzed Carbon-Hydrogen Bond Functionalization
Chiral Cp Ligands for Rhodium(III)-Catalyzed Asymmetric Carbon-Hydrogen Bond Functionalization
