Science and Engineering of Polyphenols
Fundamentals and Industrial Scale Applications
1. Edition March 2024
624 Pages, Hardcover
Wiley & Sons Ltd
ISBN:
978-1-394-20390-1
John Wiley & Sons
SCIENCE AND ENGINEERING OF POLYPHENOLS
A groundbreaking synthesis of rich and varied polyphenol research
Polyphenols are a class of compounds, found naturally in fruits and vegetables, whose flexibility and ubiquity give them a vast range of applications in pharmaceutical, environmental, and biological research and development. They play a role in diagnosing and preventing diseases from diabetes to Parkinson's to Alzheimer's and have been integral in food preservation. The field of polyphenols research has the potential to touch virtually every area of organic production.
Science and Engineering of Polyphenols provides a current and comprehensive overview of this field of research and its latest developments. Long overdue as a 'state of the field' synthesis for an area of study that has seen rapid development in recent years, this book promises to be a milestone.
Science and Engineering of Polyphenols readers will also find:
* Treatment of both natural and synthetic polyphenols
* Detailed discussion of topics including synthesis and characterization of polyphenols, electronic and molecular structure of polyphenols, and many more
* Supplementary material including websites of interest and updates on the latest research and development
Science and Engineering of Polyphenols is ideal for scholars, industrialists, and policymakers in any of the myriad areas of academia and industry touched by polyphenol research.
List of Contributors xix
Preface xxix
Editor Biography xxxi
Part I Overview of Polyphenols 1
1 Fundamentals of Polyphenols: Nomenclature, Classification and Properties 3
Sidra Subhan, Muhammad Zeeshan, Atta Ur. Rahman, and Muhmmad Yaseen
1.1 Introduction 3
1.2 A Short History of Polyphenols 5
1.3 Fundamental of Polyphenols 7
1.4 Nomenclature of Polyphenols 7
1.5 Classification of Polyphenols 8
1.6 Extraction Methods of Polyphenols 10
1.7 Solubility of Polyphenols 18
1.8 Flavor and Color of Polyphenols 22
1.9 Health-Promoting Properties of Polyphenols 24
1.10 Skin Benefits of Polyphenols 30
1.11 Conclusions 30
References 31
2 Chemistry of Polyphenols: Synthesis, Characterization, and Structure (Electronic and Molecular) and Reactivity 37
Omar Dagdag, Rajesh Haldhar, and Hansang Kim
2.1 Introduction 37
2.2 Synthesis and Characterization 38
2.3 Polyphenolics Without Intervening Atoms 39
2.4 Polyphenols with Intervening Carbon Atoms 40
2.5 Polyphenols with Intervening Heteroatoms 41
2.6 Characterization 46
2.7 Chemical Structure and Reactivity 48
2.8 Conclusion 51
References 51
3 Plant-Derived Polyphenols: Extraction, Purification, and Characterization 54
Humira Assad, Alok Kumar, and Ashish Kumar
3.1 Introduction 54
3.2 Extraction of Polyphenols 58
3.3 Purification of Polyphenols 66
3.4 Characterization of Polyphenols 67
3.5 Conclusion and Outlook 70
List of Abbreviations 71
References 72
4 Fermentation and Degradation of Polyphenols 77
Chandan K. Mandal, Palraj Kasinathan, Srikanta Sahu, Akshima, Mansi Yadav, Garima Sachdeva, Sanju Sharma, Manoj K. Banjare, and Kamalakanta Behera
4.1 Introduction 77
4.2 Plant-Based Fermented Food Products with Lactic Acid Bacteria 78
4.3 Microbial Fermentation of Food Macronutrients 80
4.4 Metabolism of Food Phenolics by Lactic Acid Bacteria 81
4.5 Polyphenols Differentially Modulate Bacterial Growth 83
4.6 Functional Food Products Based on Polyphenolic fermentation by Probiotics 84
4.7 Fermentation of Whole Grain Foods 85
4.8 Degradation of Polyphenol 88
4.9 Conclusions and Future Perspectives 93
Acknowledgments 94
List of Abbreviations 94
References 94
Part II Industrial Applications of Polyphenols 105
5 Polyphenols for Wastewater and Industrial Influents' Treatment 107
Muhammad Salman, Muhammad U. Farooq, Atta Ur. Rahman, and Muhammad Yaseen
5.1 Introduction 107
5.2 History of Natural Polyphenols 109
5.3 Types of Natural Polyphenols 109
5.4 Polyphenols in Wastewater Remediation 111
5.5 Structural and Functional Features of Polyphenols 113
5.6 Overview of Polyphenol-Based Materials 116
5.7 Applications of Natural Polyphenol-Based Material in Water Remediation 120
5.8 Conclusions, Challenges, and Prospects 125
References 126
6 Polyphenols for Anticorrosion Application 134
Shveta Sharma, Richika Ganjoo, and Ashish Kumar
6.1 Introduction 134
6.2 Anticorrosive Properties of Polyphenols: Literature Survey 138
6.3 Conclusion 151
References 152
7 Polyphenols for Dyes Application 157
Abhinay Thakur and Ashish Kumar
7.1 Introduction 157
7.2 Natural Dyes and the Need for Sustainable Alternatives 161
7.3 Chemical Structure of Polyphenols and their Dyeing Properties 168
7.4 Extraction Methods for Polyphenols from Plant Sources 175
7.5 Dyeing Mechanisms of Polyphenols 183
7.6 Applications of Polyphenols as Natural Dyes 187
7.7 Challenges and Future Prospects 195
7.8 Conclusions, Challenges, and Future Perspectives 200
References 202
8 Polyphenols for Packaging Application 211
Gianluca Viscusi and Giuliana Gorrasi
8.1 Introduction 211
8.2 Active Packaging: Coating and Thin Films 212
8.3 Phenolic Compounds 212
8.4 Classifications and Applications of Polyphenolic Compounds 215
8.5 Action Mechanism 236
8.6 Limits and Future Predictions 237
8.7 Conclusions 238
References 238
9 Polyphenols for Textile-Based Application 253
Mohd Yusuf, Vikrant Jayant, and Wasim Khan
9.1 Introduction 253
9.2 Polyphenols in Textile-Based Applications 257
9.3 Specific Functional Finishing Using Polyphenols 264
9.4 Future Outlook 268
9.5 Conclusion 269
Acknowledgement 269
References 269
10 Polyphenols for Sensing/Biosensing Application 275
Elia Grueso and Rosa M. Giráldez-Pérez
10.1 Introduction 275
10.2 Electrochemical Biosensors of Phenolic Compounds Based on Polyphenol Oxidases 278
10.3 Polyphenols for Metal Ions Sensing Applications 290
10.4 Polyphenols and Human Health 294
10.5 Conclusions and Future Perspectives 298
References 299
11 Polyphenol-based Hydrogels and Nanocomplexes: Fundamental, Properties, and Industrial Applications 315
Salima El Yakhlifi and Vincent Ball
11.1 Introduction 315
11.2 Polyphenols Grafted on Molecules Able to Undergo Gelation 316
11.3 Conclusions and Perspectives 326
References 327
12 Polyphenol-based Materials as Sensors: Recent Trends in Chemo- and Bio-sensing 330
Jing Wei, Youyou Feng, and Gen Wang
12.1 Introduction 330
12.2 Polyphenol 331
12.3 Polyphenol-based Nanomaterials and Their Derivatives 334
12.4 Sensing Applications 339
12.5 Summary and Outlook 352
Acknowledgments 352
References 353
Part III Polyphenols for Life Science Applications 359
13 Polyphenols in Control of COVID-19 361
Elyor Berdimurodov, Khasan Berdimuradov, Ashish Kumar, Omar Dagdag, Mohamed Rbaa, and Bhawana Jain
13.1 Introduction 361
13.2 Antiviral Properties of Polyphenols 366
13.3 Polyphenols Active Against COVID- 19 369
13.4 Potential Applications of Polyphenols in COVID-19 Prevention and Treatment 372
13.5 Clinical Trials and Research on Polyphenols and COVID- 19 378
13.6 Safety and Limitations of Polyphenols in COVID-19 Management 379
13.7 Conclusion 381
References 381
14 Polyphenols for Dietary Polyphenols Application 385
Elyor Berdimurodov, Khasan Berdimuradov, Ilyos Eliboev, Azimjon Choriev, Anvar Khamidov, Mukhriddin Yusufov, and Chinmurot Yodgorov
14.1 Introduction 385
14.2 Main Part 387
14.3 Conclusion and Outlook 397
References 397
15 Polyphenols for Health Management and Disease Control Applications 402
Shveta Sharma, Manu Sharma, Richika Ganjoo, and Ashish Kumar
15.1 Introduction 402
15.2 Health Benefits of Polyphenols 403
15.3 Conclusion and Future Outlook 412
References 412
16 Polyphenols as Antimicrobial (Disinfectant and Pest control) Applications 416
Vrinda, Garima Narang, Garima Pandey, Prashant Singh, and Kamlesh Kumari
16.1 Introduction 416
16.2 Pest Management 417
16.3 Disinfectants 424
16.4 Conclusion and Future Outlook 429
References 431
17 Polyphenols for Antioxidant Application: Biochemistry of Polyphenols 436
Akbar Esmaeili 43
17.1 Introduction 436
17.2 Antioxidant Activity of Polyphenols 442
17.3 Influence of Polyphenols on Antibacterial Biofilm 443
17.4 Significance of Polyphenols 445
17.5 Biochemistry of Polyphenols 446
17.6 Conclusions and Future Perspectives 448
References 448
18 Phenolic Compounds from Marine Organisms and Their Biofunctional Properties 452
Jayasri Ravichandran, Liya Babu, Kirubakaran Baskaran Jayalakshmi, Mangaiyarkarasi Manivel, Kamini Numbi Ramudu, Ganesan Ponesakki, and Nimish Mol Stephen
18.1 Introduction 452
18.2 Classification of Marine Phenols 453
18.3 Sources 459
18.4 Influence of Environmental Factors on PCs 465
18.5 Pharmaceutical and Biomedical Applications 466
18.6 Conclusion 472
Acknowledgement 472
Conflict of Interest 472
References 472
19 Polyphenols of Triberry in Dietary Supplements and Health Care 479
Palmiro Poltronieri, Sekar Sasikala, and Srinivasan Narasimhan
19.1 Introduction 479
19.2 Types of Polyphenols Found in Berries 481
19.3 Potential Health Benefits of Polyphenols from Berries 482
19.4 Conclusion 485
References 485
20 Dietary Polyphenols: Recent Trends in Its Biological Significance 489
P. Indra Arulselvi, K.R. Kavya, and M. Kesavapriya
20.1 Introduction 489
20.2 Biological Activities of Dietary Polyphenols 492
20.3 Recent Trends in Polyphenol Research 497
20.4 Conclusion and Outlook 501
References 502
21 Polyphenols for Pharmaceutical (Diagnosis, Therapies, and Prevention of Diseases) Applications 508
Nastaran Hashemzadeh, Sanaz Sajedi-Amin, Abolghasem Jouyban, and Elaheh Rahimpour
21.1 Introduction 508
21.2 Classification of Polyphenols 508
21.3 Polyphenols Applications as Potential Pharmaceutical Agents 511
21.4 Conclusion and Future Trends 524
Abbreviations 525
References 526
22 Food Additive Applications of Polyphenols 531
Richika Ganjoo, Shveta Sharma, Humira Assad, Praveen Kumar Sharma, and Ashish Kumar
21.1 Introduction 531
21.2 Polyphenols as Flavoring Agents 532
21.3 Polyphenols in Enzyme Preparations 535
21.4 Polyphenols in Preservation and Coloring 536
21.5 Polyphenols in Preservation of Meat and Aquatic Items 541
21.6 Conclusion 543
References 544
23 Biological Significance of Polyphenols as Functional Molecules in Biomaterial Preparations 548
Kalaiselvi Vinayagamurthy, Deena Praveena Kumar, Karthika Yalavarthi, Kamini Numbi Ramudu, Jayasri Ravichandran, Nimish Mol Stephen, and Ganesan Ponesakki
23.1 Introduction 548
23.2 Functional Properties of Polyphenols for Biomaterial Engineering 549
23.3 Polyphenols in Biomaterial Engineering 550
23.4 The Biological Significance of Polyphenols as Biomaterials 551
23.5 Marine Polyphenol-Based Biomaterials 569
23.6 Conclusion 571
Acknowledgments 572
Conflict of Interest 572
References 572
Index 585
Preface xxix
Editor Biography xxxi
Part I Overview of Polyphenols 1
1 Fundamentals of Polyphenols: Nomenclature, Classification and Properties 3
Sidra Subhan, Muhammad Zeeshan, Atta Ur. Rahman, and Muhmmad Yaseen
1.1 Introduction 3
1.2 A Short History of Polyphenols 5
1.3 Fundamental of Polyphenols 7
1.4 Nomenclature of Polyphenols 7
1.5 Classification of Polyphenols 8
1.6 Extraction Methods of Polyphenols 10
1.7 Solubility of Polyphenols 18
1.8 Flavor and Color of Polyphenols 22
1.9 Health-Promoting Properties of Polyphenols 24
1.10 Skin Benefits of Polyphenols 30
1.11 Conclusions 30
References 31
2 Chemistry of Polyphenols: Synthesis, Characterization, and Structure (Electronic and Molecular) and Reactivity 37
Omar Dagdag, Rajesh Haldhar, and Hansang Kim
2.1 Introduction 37
2.2 Synthesis and Characterization 38
2.3 Polyphenolics Without Intervening Atoms 39
2.4 Polyphenols with Intervening Carbon Atoms 40
2.5 Polyphenols with Intervening Heteroatoms 41
2.6 Characterization 46
2.7 Chemical Structure and Reactivity 48
2.8 Conclusion 51
References 51
3 Plant-Derived Polyphenols: Extraction, Purification, and Characterization 54
Humira Assad, Alok Kumar, and Ashish Kumar
3.1 Introduction 54
3.2 Extraction of Polyphenols 58
3.3 Purification of Polyphenols 66
3.4 Characterization of Polyphenols 67
3.5 Conclusion and Outlook 70
List of Abbreviations 71
References 72
4 Fermentation and Degradation of Polyphenols 77
Chandan K. Mandal, Palraj Kasinathan, Srikanta Sahu, Akshima, Mansi Yadav, Garima Sachdeva, Sanju Sharma, Manoj K. Banjare, and Kamalakanta Behera
4.1 Introduction 77
4.2 Plant-Based Fermented Food Products with Lactic Acid Bacteria 78
4.3 Microbial Fermentation of Food Macronutrients 80
4.4 Metabolism of Food Phenolics by Lactic Acid Bacteria 81
4.5 Polyphenols Differentially Modulate Bacterial Growth 83
4.6 Functional Food Products Based on Polyphenolic fermentation by Probiotics 84
4.7 Fermentation of Whole Grain Foods 85
4.8 Degradation of Polyphenol 88
4.9 Conclusions and Future Perspectives 93
Acknowledgments 94
List of Abbreviations 94
References 94
Part II Industrial Applications of Polyphenols 105
5 Polyphenols for Wastewater and Industrial Influents' Treatment 107
Muhammad Salman, Muhammad U. Farooq, Atta Ur. Rahman, and Muhammad Yaseen
5.1 Introduction 107
5.2 History of Natural Polyphenols 109
5.3 Types of Natural Polyphenols 109
5.4 Polyphenols in Wastewater Remediation 111
5.5 Structural and Functional Features of Polyphenols 113
5.6 Overview of Polyphenol-Based Materials 116
5.7 Applications of Natural Polyphenol-Based Material in Water Remediation 120
5.8 Conclusions, Challenges, and Prospects 125
References 126
6 Polyphenols for Anticorrosion Application 134
Shveta Sharma, Richika Ganjoo, and Ashish Kumar
6.1 Introduction 134
6.2 Anticorrosive Properties of Polyphenols: Literature Survey 138
6.3 Conclusion 151
References 152
7 Polyphenols for Dyes Application 157
Abhinay Thakur and Ashish Kumar
7.1 Introduction 157
7.2 Natural Dyes and the Need for Sustainable Alternatives 161
7.3 Chemical Structure of Polyphenols and their Dyeing Properties 168
7.4 Extraction Methods for Polyphenols from Plant Sources 175
7.5 Dyeing Mechanisms of Polyphenols 183
7.6 Applications of Polyphenols as Natural Dyes 187
7.7 Challenges and Future Prospects 195
7.8 Conclusions, Challenges, and Future Perspectives 200
References 202
8 Polyphenols for Packaging Application 211
Gianluca Viscusi and Giuliana Gorrasi
8.1 Introduction 211
8.2 Active Packaging: Coating and Thin Films 212
8.3 Phenolic Compounds 212
8.4 Classifications and Applications of Polyphenolic Compounds 215
8.5 Action Mechanism 236
8.6 Limits and Future Predictions 237
8.7 Conclusions 238
References 238
9 Polyphenols for Textile-Based Application 253
Mohd Yusuf, Vikrant Jayant, and Wasim Khan
9.1 Introduction 253
9.2 Polyphenols in Textile-Based Applications 257
9.3 Specific Functional Finishing Using Polyphenols 264
9.4 Future Outlook 268
9.5 Conclusion 269
Acknowledgement 269
References 269
10 Polyphenols for Sensing/Biosensing Application 275
Elia Grueso and Rosa M. Giráldez-Pérez
10.1 Introduction 275
10.2 Electrochemical Biosensors of Phenolic Compounds Based on Polyphenol Oxidases 278
10.3 Polyphenols for Metal Ions Sensing Applications 290
10.4 Polyphenols and Human Health 294
10.5 Conclusions and Future Perspectives 298
References 299
11 Polyphenol-based Hydrogels and Nanocomplexes: Fundamental, Properties, and Industrial Applications 315
Salima El Yakhlifi and Vincent Ball
11.1 Introduction 315
11.2 Polyphenols Grafted on Molecules Able to Undergo Gelation 316
11.3 Conclusions and Perspectives 326
References 327
12 Polyphenol-based Materials as Sensors: Recent Trends in Chemo- and Bio-sensing 330
Jing Wei, Youyou Feng, and Gen Wang
12.1 Introduction 330
12.2 Polyphenol 331
12.3 Polyphenol-based Nanomaterials and Their Derivatives 334
12.4 Sensing Applications 339
12.5 Summary and Outlook 352
Acknowledgments 352
References 353
Part III Polyphenols for Life Science Applications 359
13 Polyphenols in Control of COVID-19 361
Elyor Berdimurodov, Khasan Berdimuradov, Ashish Kumar, Omar Dagdag, Mohamed Rbaa, and Bhawana Jain
13.1 Introduction 361
13.2 Antiviral Properties of Polyphenols 366
13.3 Polyphenols Active Against COVID- 19 369
13.4 Potential Applications of Polyphenols in COVID-19 Prevention and Treatment 372
13.5 Clinical Trials and Research on Polyphenols and COVID- 19 378
13.6 Safety and Limitations of Polyphenols in COVID-19 Management 379
13.7 Conclusion 381
References 381
14 Polyphenols for Dietary Polyphenols Application 385
Elyor Berdimurodov, Khasan Berdimuradov, Ilyos Eliboev, Azimjon Choriev, Anvar Khamidov, Mukhriddin Yusufov, and Chinmurot Yodgorov
14.1 Introduction 385
14.2 Main Part 387
14.3 Conclusion and Outlook 397
References 397
15 Polyphenols for Health Management and Disease Control Applications 402
Shveta Sharma, Manu Sharma, Richika Ganjoo, and Ashish Kumar
15.1 Introduction 402
15.2 Health Benefits of Polyphenols 403
15.3 Conclusion and Future Outlook 412
References 412
16 Polyphenols as Antimicrobial (Disinfectant and Pest control) Applications 416
Vrinda, Garima Narang, Garima Pandey, Prashant Singh, and Kamlesh Kumari
16.1 Introduction 416
16.2 Pest Management 417
16.3 Disinfectants 424
16.4 Conclusion and Future Outlook 429
References 431
17 Polyphenols for Antioxidant Application: Biochemistry of Polyphenols 436
Akbar Esmaeili 43
17.1 Introduction 436
17.2 Antioxidant Activity of Polyphenols 442
17.3 Influence of Polyphenols on Antibacterial Biofilm 443
17.4 Significance of Polyphenols 445
17.5 Biochemistry of Polyphenols 446
17.6 Conclusions and Future Perspectives 448
References 448
18 Phenolic Compounds from Marine Organisms and Their Biofunctional Properties 452
Jayasri Ravichandran, Liya Babu, Kirubakaran Baskaran Jayalakshmi, Mangaiyarkarasi Manivel, Kamini Numbi Ramudu, Ganesan Ponesakki, and Nimish Mol Stephen
18.1 Introduction 452
18.2 Classification of Marine Phenols 453
18.3 Sources 459
18.4 Influence of Environmental Factors on PCs 465
18.5 Pharmaceutical and Biomedical Applications 466
18.6 Conclusion 472
Acknowledgement 472
Conflict of Interest 472
References 472
19 Polyphenols of Triberry in Dietary Supplements and Health Care 479
Palmiro Poltronieri, Sekar Sasikala, and Srinivasan Narasimhan
19.1 Introduction 479
19.2 Types of Polyphenols Found in Berries 481
19.3 Potential Health Benefits of Polyphenols from Berries 482
19.4 Conclusion 485
References 485
20 Dietary Polyphenols: Recent Trends in Its Biological Significance 489
P. Indra Arulselvi, K.R. Kavya, and M. Kesavapriya
20.1 Introduction 489
20.2 Biological Activities of Dietary Polyphenols 492
20.3 Recent Trends in Polyphenol Research 497
20.4 Conclusion and Outlook 501
References 502
21 Polyphenols for Pharmaceutical (Diagnosis, Therapies, and Prevention of Diseases) Applications 508
Nastaran Hashemzadeh, Sanaz Sajedi-Amin, Abolghasem Jouyban, and Elaheh Rahimpour
21.1 Introduction 508
21.2 Classification of Polyphenols 508
21.3 Polyphenols Applications as Potential Pharmaceutical Agents 511
21.4 Conclusion and Future Trends 524
Abbreviations 525
References 526
22 Food Additive Applications of Polyphenols 531
Richika Ganjoo, Shveta Sharma, Humira Assad, Praveen Kumar Sharma, and Ashish Kumar
21.1 Introduction 531
21.2 Polyphenols as Flavoring Agents 532
21.3 Polyphenols in Enzyme Preparations 535
21.4 Polyphenols in Preservation and Coloring 536
21.5 Polyphenols in Preservation of Meat and Aquatic Items 541
21.6 Conclusion 543
References 544
23 Biological Significance of Polyphenols as Functional Molecules in Biomaterial Preparations 548
Kalaiselvi Vinayagamurthy, Deena Praveena Kumar, Karthika Yalavarthi, Kamini Numbi Ramudu, Jayasri Ravichandran, Nimish Mol Stephen, and Ganesan Ponesakki
23.1 Introduction 548
23.2 Functional Properties of Polyphenols for Biomaterial Engineering 549
23.3 Polyphenols in Biomaterial Engineering 550
23.4 The Biological Significance of Polyphenols as Biomaterials 551
23.5 Marine Polyphenol-Based Biomaterials 569
23.6 Conclusion 571
Acknowledgments 572
Conflict of Interest 572
References 572
Index 585
Chandrabhan Verma, PhD, is a researcher at the Department of Chemical Engineering, Khalifa University of Science and Technology, Abu Dhabi, United Arab Emirates. He has researched and published extensively on the synthesis and design of environmentally-friendly corrosion inhibitors.
